Mixing colors is not like when we were in grade school ... red and blue doesn't always make purple. It depends on the shade of red, and the shade of blue. Proficiency in color mixing takes time, trial and error. But once you've got it, your painting journey will become much more enjoyable. Below is a color chart that may help you. I suggest you make one of your own, with your own colors. Unfortunately, accuracy in color is rare, in that there are color shifts from manufacturer to manufacturer. Additionally, some colors from the same brand may shift slightly from time to time, depending on their source of pigment and many other factors.
Once you get proficient in mixing colors, it becomes easier to paint with a limited palette, which is a major convenience when painting out-of-doors or in a classroom. A limited palette also leaves lots of room on your palette for mixing, and makes for a less cluttered work table. I do hope you make your own color chart with your own colors--you will find it very helpful.
NOTE - Click on images to enlarge.
Here's a watercolor chart I made up for a class that may be helpful to you watercolorists:
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